Synthesis and Structure of the Coordination Polymer with One-dimensional Zigzag Chain Extended by Fe(ⅲ)-CN-Cu(ⅱ) Linkages 铁氰根桥联的一维链状大环配位聚合物的合成及结构
Compound 1 exhibits a 1D zigzag chain structure, while 2 being 1D linear chain, which is resulted from different ligands. 化合物1呈一维之字链状结构,化合物2为一维一字链结构。
While in copper ( II) complex, the mononuclear [ Cu ( HSas)( H2O)] repeating units form a 1D zigzag chain and further extended by strong intermolecular hydrogen bondings to form a 2D sheet. 而在Cu(Ⅱ)配合物中,单核的铜不对称单元形成了一个一维的zigzag链,这些一维链通过氢键形成了二维的网状结构。